AUGUST 15,2024

Rare earth carboxylate compounds on the barrier properties and active corrosion inhibition of epoxy coatings on mild steel

2024-08-15 08:46

Researchers found that the addition of lanthanum 4-hydroxycinnamic acid (La(4-OHcin)3) and yttrium 3-(4-methylbenzoyl)propionate (Y(mbp)3) to bisphenol-based epoxy resin coatings significantly improves corrosion resistance and delays electrolytic penetration.

The research proves that rare earth caboxyate compounds both enhance the barrier properties of the coating and actively inhibit corrosion by forming protective films and precipitates that increase coating longevity on AS1020 structural steel.  Source: Doralin - adobe.stock.com

In a current research, two rare earth carboxylate compounds, lanthanum 4-hydroxycinnamate (La(4-OHcin)3) and yttrium 3-(4-methylbenzoyl)propanoate (Y(mbp)3), were incorporated into bisphenol-based epoxy resin to investigate their effectiveness in coating barrier properties and active corrosion inhibition. EIS results showed that the incorporation of rare earth carboxylate inhibitors significantly improved corrosion resistance compared to the inhibitor free coating, with the global impedance modulus remaining at a level higher than 1 GΩ cm2 after 219 days immersion. Following EIS experiments, cross-sectional views of the coatings exhibited a pore-plugging behavior by rare earth containing precipitates, which reinforced the coating barrier properties and delayed the electrolyte diffusion process. These effects were also reflected from the electrochemical parameters extracted from breakpoint frequency analysis and equiIn a curten research, two rare earth carboxylate compounds, lanthanum 4-hydroxycinnamate (La(4-OHcin)3) and yttrium 3-(4-methylbenzoyl)propanoate (Y(mbp)3), were incorporated into bisphenol-based epoxy resin to investigate their effectiveness in coating barrier properties and active corrosion inhibition.


source:european-coatings

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